Yes, you most certainly can! With a Thriday Visa Debit Card, you will be able to withdraw cash from your transaction account at all ATMs around Australia. Similar to other debit cards, there is a daily limit for cash withdrawal of $1,000 per day which resets at midnight Sydney time.
Thriday has an arrangement with Australia Post that allows you to deposit or withdraw cash anywhere Bank@Post is supported. Bank@Post is available at participating Post Offices all around Australia. You can find your nearest participating location here: https://auspost.com.au/money-insurance/banking-and-payments/bank-at-post
When you make a withdrawal or deposit through your Transaction Account at a Bank@Post (Australia Post) outlet, a $3.25 fee will apply. This fee is also applicable if your transaction is declined.